超高分子量聚乙烯纤维防护机理研究综述

莫根林1,刘 静2,金永喜3,闫文敏3

(1.杭州职业技术学院,浙江 杭州 3100182;2.江苏大学 先进制造研究院,江苏 镇江 212013;3.瞬态冲击技术国防科技重点实验室,北京 102202)

摘要:超高分子量聚乙烯纤维具有密度低、力学性能高的优点,在防弹衣领域获得了广泛应用。本文综述了人们就该纤维、该纤维的单向布以及其复合材料靶板的力学性能开展的大量实验研究、理论研究和数值模拟研究,从不同角度揭示了该纤维的力学特性;在超高分子量聚乙烯纤维及复合材料靶板的本构模型和破坏准则方面,尚需考虑材料的应变率效应和复杂应力状态的影响,才能进一步揭示该纤维的防护机理,指导超高分子量聚乙烯防护靶板的优化设计。

关键词:超高分子量聚乙烯;纤维;单向布;复合靶板;防护;力学特性

1 引言

自第一次世界大战以来,防弹衣成为单兵防护装备的重要组成部分,在减少部队作战人员伤亡、提高单兵生存能力、增强作战效能方面发挥着重要作用。高性能纤维增强复合材料由于具有重量轻、防护性能高、无二次杀伤效应等优点,在软体防弹衣和硬体防弹衣中获得了广泛应用[1]

纤维是高性能纤维增强复合材料结构的主要承载部分,它经历了从高强尼龙、高强玻璃纤维、碳纤维到芳纶、超高分子量聚乙烯(UHMWPE)等特种纤维的更新换代过程。表1为各种纤维的静态拉伸力学特性,UHMWPE纤维具有较高的断裂伸长率(3.7%),比强度是芳纶纤维的1.48倍,具有良好的能量吸收特性。同等面密度情况下,防弹能力比芳纶纤维抗弹复合材料高约25%[5-7]。在此背景下,通过研究UHMWPE纤维增强复合材料靶板的防护机理提高靶板的防护性能成为当前研究热点。

表1 纤维的静态力学特性[2-4]

Table 1 Static mechanical properties of fibers[2-4]

名称密度/(g·cm-3)弹性模量/GPa断裂伸长率/%断裂强度/GPaPA661.146200.9玻璃纤维2.54865.34.6碳纤维1.762401.43.4芳纶1.451242.52.76PBO1.561803.55.8UHMWPE0.961003.73.1

2 UHMWPE纤维的力学性能

Kromm等[8]研究了应变率为0.001~0.01 s-1时70~140 ℃温度下SK75纤维束的力学特性;Huang[9]研究了UHMWPE纤维束在25 ℃、70 ℃下应变率为300 s-1和700 s-1时的力学性能;Russell等[10]研究了应变率为0.001~0.1 s-1时UHMWPE纤维束的力学特性;Koh等[11]采用Hopkinson杆研究了Spectra 900纤维束在应变率为100~400 s-1左右时的力学性能;张华鹏[12]利用Hopkinson杆研究了SK65纤维束在应变率为900 s-1时的力学性能和破坏模式,并利用弱环理论分析了纤维的强度分布特性;王庭辉等[13]采用Hopkinson杆测量了UHMWPE纤维在应变率2 500 s-1左右时纤维束的力学性能。上述研究结果表明:UHMWPE纤维具有显著的温度效应、应变率效应和尺度效应,即随着温度升高,纤维的弹性模量降低,70-140 ℃时其拉伸强度明显降低;纤维的弹性模量随应变率的增加而降低;拉伸强度对低应变率不敏感,对高应变率敏感;纤维的断裂应变随应变率的增加而降低;纤维束的拉伸强度只有纤维强度的1/3~1/2,延伸率却比纤维的高2.7倍以上。

由于UHMWPE纤维是高度取向的各向异性材料,一些研究者对UHMWPE纤维其他非拉伸方向的力学性能进行了研究。Sun[14]研究了Spectra纤维的剪切-拉伸双向静态和动态应力-应变关系,结果表明:随着剪应变增加,拉伸强度减小。Hudspeth等[15]研究了SK76纤维在剪切-拉伸作用下纤维的力学特性,结果表明:随着拉应力增加,纤维的剪切强度增加、失效应变减小。Guo等[16]研究了SK76纤维的横向静态压缩性能,利用Hopkinson杆研究其冲击压缩性能,结果表明:纤维在压缩应变小于50%时的应力-应变曲线没有显著的应变率效应。

3 UHMWPE单向布的力学性能

按照预制体的结构,纤维增强复合材料可分为一维连续结构、二维平面结构和三维整体结构;按照预制体的织造工艺,又可分为编织、机织、针织和缝合等类型。为避免纤维在织造过程中的强度损失,UHMWPE纤维主要以单向布或正交复合的单向布——无纬布(两层单向布复合而成)作为复合靶板的组成单元。

曾庆敦[17]和李红周等[18]总结归纳了经典剪切滞后理论、链式统计模型、裂纹扩展模型、蒙特卡洛模拟在单向复合材料中的应用;Romanov等[19]、Ismail等[20-21]和Elnekhaily等[22]考虑单向布中纤维的不均匀分布特性,数值模拟研究了单向布的拉伸特性;Nazarian等[23]研究了无纬布的面内剪切应力-应变关系,假设无纬布层内由互补相连的筋板构成,数值模拟分析了无纬布的剪切变形情况;宋娜[24]和韩学群[25]通过内聚力单元法研究了准静态条件下无纬布层合板的层间分层现象;针对UHMWPE纤维表面非极性、与树脂粘结性能较差的缺陷,肖干[26]、王成忠等[27]、黄献聪[28]、邱军等[29]分别采用低温等离子表面处理、液相氧化-涂覆、电子束辐照和紫外接枝等工艺改善了UHMWPE纤维复合材料的力学性能;刘术佳[5]和Neema等[30]则分别研究了微颗粒改性树脂和纳米改性树脂对UHMWPE复合材料力学性能的影响。上述研究表明,单向布和无纬布的力学特性不仅和纤维、树脂本身的力学特性有关,还和纤维与树脂的结合界面、纤维布中纤维的分布特性等因素有关。

4 UHMWPE单向布复合靶板的力学性能

为达到相应的防护性能要求,单向布或无纬布通常以复合靶板的形式使用,主要包括:软防护靶板和硬质层合板(以单层之间是否粘结区分)。按照研究手段的不同,它们抗侵彻机理的研究可分为实验研究,理论研究和数值模拟研究。

4.1 实验研究

对于软防护靶板,Chocron等[31]研究了弹头侵彻条件下单向布窄条和无纬布的变形运动规律;Karthikeyan等[32]研究了UHMWPE单向布铺层角度对防护性能的影响规律。文献[33-34]研究了UHMWPE改性树脂基无纬布的拉伸强度、抗弯强度和层间剥离强度;梁子青等[35]研究了基体含量对UHMWPE多层无纬布抗手枪弹侵彻性能的影响;高恒等[36]研究了UHMWPE纤维平纹织物与无纬布复合靶板的抗弹性能。Tan等[37]对比研究了平头弹和尖头弹侵彻Spectra单层无纬布的破坏模式。

对于硬质层合板,Lässig等[38]和Long等[39]通过实验设计获得了UHMWPE层合板的本构模型和破坏准则;李思辉[40]通过落锤冲击实验研究了不同铺层角度UHMWPE层合板的能量吸收性能;张典堂等[41]通过落锤冲击实验研究了UHMWPE层合板的破坏损伤模式和剩余压缩强度;Yang等[42]和Karthikeyan等[43]分别研究了弹头和球形破片侵彻层合板的破坏模式;Karthikeyan等[44]和王晓强等[45]分别研究了立方体破片侵彻性能随层合板厚度和破片入射角度的变化规律;Tomasz等[46]对比研究了2种UHMWPE纤维层合板的变形破坏模型。Zhang等[47-48]对比研究了UHMWPE无纬布、二维平纹和三维正交复合材料的防弹性能、破坏模式和背板鼓包变形规律。张佐光等[49],孙志杰等[50]和张大兴等[51]研究了UHMWPE层合板弹道吸能随面密度、弹速、成型压力、树脂基体含量的变化规律。

上述研究表明,侵彻条件下UHMWPE复合材料靶板会发生层间分层、层内开裂、纤维拔出等物理现象;靶板的防护性能与众多因素有关,包括树脂的种类与含量、纤维的力学性能、纤维与树脂的结合性能、靶板的结构和尺寸、弹头的外形和结构、弹头的入射角度和速度等。为获得符合要求的靶板,设计者需要消耗大量的精力进行实验研究。为降低实验成本,研究人员从理论和数值模拟方面对靶板的防护机理进行了研究。

4.2 理论研究

Navarro等[52]、Parga-Landa等[53]和Sánchez-Gálvez等[54]假设纤维为弹性材料,不考虑软防护靶板的分层效应,基于波的传播理论建立了弹头正侵彻单向布和平纹织物的理论模型;Phoenix等[55]考虑UHMWPE和Kevlar复合靶板的分层现象,建立了弹头正侵彻复合靶板的理论模型;Long等[56]将弹头侵彻靶板的物理过程分为剪切阶段和背板鼓包阶段,建立了弹头侵彻靶板的弹道极限模型;Sánchez-Gálvez等[57]基于波传播理论,分析了侵彻过程中靶标主纱线、侧纱线的变形能和动能、靶板的层间开裂和剪切冲塞效应,建立了弹头斜侵彻无纬布层合板的理论模型;Chocron Benloulo等[58]和莫根林等[59]基于弹塑性理论分析了复合材料背板的变形运动,建立了弹头侵彻陶瓷/复合材料靶板的理论模型。总体而言,这些弹道模型在一定程度上满足了靶板防护性能的评估要求。由于模型通常没有考虑弹头材料以及靶板材料的本构模型和破坏准则,其适应范围有待进一步的实验验证。

4.3 数值模拟研究

Lässig等[38]和Long等[39]建立了球形破片侵彻UHMWPE无纬布层合板的宏观有限元模型,分析了模型参数对弹道极限的影响规律;为进一步分析靶板的纤维断裂、滑移、抽拔等破坏现象,Utomo[60]采用索单元作为纤维束的近似单元,建立了单向布的细观有限元模型;Barauskas等[61]在弹头冲击区域使用纤维和树脂构成的窄带模型替代单向布真实结构,在远离冲击区域使用均质正交各向异性壳单元替代单向布,实现了弹头侵彻无纬布的多尺度模拟。卓星伯通过建立单向布的纤维束模型、均质材料模型和两者的混合模型,对比研究了弹头侵彻单向布软防护靶板的运动规律。Chocron等[62-63]利用宏观有限元模型和窄带模型研究了弹头侵彻多层单向布的运动过程。Kudryavtsev等[64]建立了无纬布的窄带模型,并通过数值模拟研究了弹头侵彻多层无纬布的运动过程。上述研究表明,有限元模型考虑了靶板的组织结构和材料力学特性,在弹道极限和靶板鼓包变形方面能够获得较好的模拟结果。然而,模型中的本构模型和破坏准则的相关参数通常与材料的加工处理过程有关,现有研究尚未有效揭示它们之间的定量关系。

5 结论

1)UHMWPE纤维具有比强度、比模量高的优点,在现代国防和高科技产业中发挥着越来越重要的作用,特别是在防弹装备上占据重要位置,具有极大的市场前景。

2)为设计出性能优越的防护装备,需要继续在本构模型和破坏准则方面探讨UHMWPE纤维及其复合材料靶板的力学特性,拓宽现有研究成果的适用范围,进一步研究UHMWPE单向布复合靶板在复杂力学状态下的力学响应和UHMWPE单向布复合靶板在侵彻条件下的破坏准则,尤其是纤维的断裂和靶板的分层鼓包准则。

3)在优化防弹装备的过程中,不仅需要注意制备工艺的影响,还需要充分发挥其他先进材料的优点,通过UHMWPE纤维和这些材料的复合,制备出各方面性能均较为优越的防护装备。

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Review on Protective Mechanism of UHMWPE Fiber

MO Genlin1,LIU Jing2,JIN Yongxi3,YAN Wenmin3

(1.Hangzhou Vocational & Technical College, Zhejiang 3100182, China;2.Institute of Advanced Manufacturing, Jiangsu University, Zhenjiang 212013, China; 3.Key Laboratory of Transient Shock, Beijing 102202, China)

Abstract: Ultra high molecular weight polyethylene(UHMWPE)fiber has the advantages of low density and high mechanical properties, which has been widely used in the field of bulletproof vests.At present, a lot of experimental, theoretical and numerical studies have been carried out on the mechanical properties of the fiber, unidirectional cloth and composite target plate.These studies revealed the mechanical properties of UHMWPE fibers from different angles.In the aspect of constitutive model and failure criterion of UHMWPE fibers and composite target plates, the strain rate effect and the influence of complex stress state should be considered, to further reveal the protection mechanism of UHMWPE fiber and guide the optimal design of UHMWPE protective target plates.

Key words: ultra high molecular weight polyethylene; fiber; uni-direction cloth; laminate; protection; mechanical properties

本文引用格式:莫根林,刘静,金永喜,等.超高分子量聚乙烯纤维防护机理研究综述[J].兵器装备工程学报,2021,42(10):23-28.

Citation format:MO Genlin,LIU Jing,JIN Yongxi, et al.Review on Protective Mechanism of UHMWPE Fiber[J].Journal of Ordnance Equipment Engineering,2021,42(10):23-28.

中图分类号:TJ9

文献标识码:A

文章编号:2096-2304(2021)10-0023-06

收稿日期:2020-12-16;修回日期:2021-01-01

基金项目:江苏大学高级人才启动基金项目(15JDG038);江苏省高校自然科学基金项目(19KJB130003);国防科技重点实验室预研基金项目(601010417)

作者简介:莫根林(1987—),男,博士,副研究员,E-mail:550402699@qq.com。

doi:10.11809/bqzbgcxb2021.10.004

科学编辑 卢玉斌 博士(中国科学院泉州装备制造研究中心研究员、硕导)

责任编辑 周江川